一种星敏感器安装误差标定模型仿真研究

安装误差对星敏感器姿态确定精度有严重影响,需对其进行有效的标定与补偿。为此提出了一种以星敏感器量测信息为依据的安装误差快速标定模型和方法。该方法通过分析星敏感器输出的姿态信息与安装误差之间耦合关系,建立四位置下星敏感器测量信息及相对位置关系与安装误差的观测模型,在此基础上推导了安装误差标定及补偿算法。仿真表明,该法能够实现对星敏感器安装误差的高精度标定,可有效提高星光天文定姿的精度,对星敏感器的高精度应用具有重要的理论意义和实际参考价值。     

Uniform star‐polystyrene nanoparticles prepared by emulsion atom transfer radical polymerization

Pentaerythritol (PT) was converted into four‐arm initiator pentaerythritol tetrakis(2‐chloropropionyl) (PT‐Cl) via reaction with 2‐chloropropionyl chloride. Uniform (monodisperse) star‐polystyrene nanoparticles were prepared by emulsion atom transfer radical polymerization of styrene, using PT‐Cl/CuCl/bpy (bpy is 2,2′‐dipyridyl) as the initiating system. The structures of PT‐Cl and polymer were characterized by Fourier transform infrared spectroscopy and nuclear magnetic resonance. The morphology, size and size distribution of the star‐polystyrene nanoparticles were characterized by transmission electron microscopy, atomic force microscopy and photon correlation spectroscopy. It was found that the average diameters of star‐polystyrene nanoparticles were smaller than 100 nm (30–90 nm) and monodisperse; moreover, the particle size could be controlled by the monomer/initiator ratio and the surfactant concentration. The average hydrodynamic diameter (D_h) of the nanoparticles increased gradually on increasing the ratio of styrene to PT‐Cl and decreased on enhancing the surfactant concentration or increasing the catalyst concentration. Copyright © 2011 Society of Chemical Industry     

Star‐shaped amphiphilic block polyurethane with pentaerythritol core for a hydrophobic drug delivery carrier

To obtain polyurethane micelles with excellent stability as a drug delivery carrier, star‐shaped amphiphilic block polyurethane (SAPU) was successfully synthesized by the ‘arm‐first’ method, using methoxypoly(ethylene glycol) and poly(ε‐caprolactone) diol as soft segments, hexamethylene diisocyanate as hard segments and pentaerythritol as the core. The structure of the SAPU was characterized by Fourier transform infrared spectroscopy, ¹H NMR spectroscopy and gel permeation chromatography. The micellization behaviour and micelle properties of SAPU were measured by the pyrene fluorescence probe technique, ¹H NMR, SEM and dynamic light scattering. The results indicated that SAPU could self‐assemble to form nanomicelles in aqueous solution and that the micelles showed excellent stability upon dilution and storage. Indometacin as a model drug could be incorporated into SAPU micelles and be released sustainedly. Meanwhile, the hydrophilic segment content and the molecular weight of SAPU had effects on the micelle properties. In addition, SAPU exhibited good cytocompatibility estimated by methylthiazole‐tetrazolium assay. © 2016 Society of Chemical Industry     

Facile synthesis and characterization of star‐shaped polystyrene: self‐condensing atom transfer radical copolymerization of N‐[4‐(α‐bromoisobutyryloxy)phenyl]maleimide and styrene

BACKGROUND: Generation of stars around in situ formed cores provides a facile approach to star‐shaped polymers. Therefore the self‐condensing atom transfer radical copolymerization (SCATRCP) of N‐[4‐(α‐bromoisobutyryloxy)phenyl]maleimide (BiBPM) and a large excess of styrene (St) was investigated. RESULTS: BiBPM and St formed a charge transfer complex (CTC), which underwent the SCATRCP, leading to the branched core initiating the atom transfer radical polymerization of St, finally giving star‐shaped polystyrene (PS). Kinetic and structural study showed that a higher dosage of BiBPM resulted in an enhanced polymerization rate, a higher degree of branching and a larger number of short PS arms. Differential scanning calorimetry suggested that the glass transition temperature of the star‐shaped PS decreased with molecular weight. Melt rheometry showed that even a slightly branched architecture of the PS led to a significantly lower viscosity; both the melt flow index and the activation energy increased with the degree of branching. CONCLUSION: Due to the preferential consumption of BiBPM and formation of a CTC, even a very low dosage of BiBPM could lead to star‐shaped PS, which, in comparison with linear analogues, could possess much better melt fluidity. Copyright © 2008 Society of Chemical Industry     

Low end‐to‐end delay fuzzy networking protocol for mobile wireless sensing

Because of the practical limitations of the energy and processing capabilities, the deployment of many Wireless Sensor Networks (WSN) is facing two main challenges of increasing network lifetime and reducing End to End Delay (EED) which become critical when the nodes are mobile and use non‐rechargeable energy sources. One way to help to extend network lifetime is using fuzzy logic in a form of artificial intelligence. To this end we propose a new routing protocol for using mobile WSNs, which holds the nodes in an equal level of energy and decreases energy dissipation of the network. An optimum path is selected based on the cost of each node to increase network lifetime. In order to lessen EED, we also attempt to design a novel zoning‐scheme for the network area. In this scheme, zonation is dynamic and works based on the Data Link (DL) position. The simulation result shows a significant improvement in lifetime and EED by proposed protocol compared with existing protocols. Copyright © 2016 John Wiley & Sons, Ltd.     

滤波电路电容器联接方法对滤波效果影响的分析

文章对滤波电路电容器的联接方法进行分析,得出联接方法对谐波效果有很大影响的结论。尤其是零序谐波,采用角型连接的电容器,没有滤波作用。目前大部分厂商采用角型连接电容器串接14．5％电抗器滤除3次谐波,其实作用甚微。提出了解决方法和需注意事项。     

A novel initiating system for ring‐opening polymerization of ε‐caprolactone: Synthesis of triarm star‐shaped poly(ε‐caprolactone)

The rare earth compound, scandium trifluoromethanesulfonate [Sc(OTf)₃], has been used as a water‐tolerant catalyst for the synthesis of star‐shaped poly(ε‐caprolactone)s (SPCLs) with trimethylol propane as trifunctional initiator in solvent at 40°C. Triarm SPCLs have been successfully prepared. The molar mass of SPCLs were determined by end‐group ¹H NMR analyses, which could be well controlled by the molar ratio of the monomer to the initiator, and were independent of the amount of Sc(OTf)₃ used. Differential scanning calorimetry analyses suggested that the maximal melting point, the cold crystallization temperature, and the degree of crystallinities of SPCLs increased with the increasing of the molar mass and were lower than the linear poly(ε‐caprolactone) (LPCL) with similar molar mass. Furthermore, polarized optical microscopy indicated that LPCL showed fast crystallization rate and good spherulitic morphology with apparent Maltese cross pattern, whereas SPCLs exhibit much lower crystallization rate and poor spherulitic morphology. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010